Comment on “Observation of the Marcus Inverted Region for Bimolecular Photoinduced Electron-Transfer Reactions in Viscous Media”

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Comment on "Observation of the Marcus Inverted Region for Bimolecular Photoinduced Electron-Transfer Reactions in Viscous Media".

The general observation of Marcus inverted region (MIR) for bimolecular electron-transfer (ET) reactions in different viscous media, e.g., micelles, reverse micelles, vesicles, ionic liquids, DNA scaffold, etc. has been doubted in some recent publications arguing limitations in Stern-Volmer (SV) analysis to account for the static and transient stages of quenching in these slow diffusing media. ...

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ژورنال

عنوان ژورنال: The Journal of Physical Chemistry B

سال: 2016

ISSN: 1520-6106,1520-5207

DOI: 10.1021/acs.jpcb.6b06610